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 Karl Franzens University Graz

Graz University of Technology 

Irreversibility and non-equilibrium fluctuations at the nanoscale
Prof. Christoph Dellago
Universität Wien
17:15 - 18:15 Tuesday 28 April 2015 TUG P2

Fluctuation theorems and non-equilibrium work relations, exact result that characterize the fluctuations of heat, work and entropy in non-equilibrium processes, have significantly improved our understanding of how the Second Law of Thermodynamics operates at the nanoscale. Here, we apply this framework to investigate the fluctuations in relative entropy production for the relaxation of a laser-trapped nanoparticle from a non-equilibrium steady state towards equilibrium [1,2]. Because of the low damping, the dynamics of this nanomechanical system can be precisely controlled and the oscillator can be cooled by parametric feedback. Based on the steady state distribution, which is determined analytically based on the equations of motion of the system, we determine the change of relative entropy observed after the feedback has been switched off. The statistics of heat transfer measured in repeated relaxation experiments obeys a fluctuation theorem derived for this particular situation. I will discuss the relevance of our work for the study of transitions between arbitrary non-equilibrium steady states.

[1] J. Gieseler, R. Quidant, C. Dellago and L. Novotny, „Dynamic relaxation of a levitated nanoparticle from a non-equilibrium steady state“, Nature Nanotechnology 9, 358-364 (2014).

[2] J. Gieseler, L. Novotny, C. Moritz, C. Dellago, “Non-equilibrium steady state of a driven levitated particle with feedback cooling“, arXiv:1502.07834 (2015).