Engineering Metal-Organic Frameworks for device fabrication
Prof. Dr. Paolo Falcaro
CSIRO and Institute of Physical and Theoretical Chemistry, Graz University of Technology
17:15 - 18:15 Tuesday 03 May 2016 TUG P2 Metal organic frameworks (MOFs) are a class of ultra-porous materials with exceptionally high accessible surface area due to the framework produced by the inorganic nodes coordinated by organic bridging ligands.[1,2] A number of increasing studies are investigating Metal-Organic Frameworks (MOFs) for a variety of functional applications including sensing, microelectronics, energy production, drug delivery and microfluidics.[3] However, MOF-based device fabrication requires synthetic protocols for the controlled functionalization of the ultra-porous crystals and their integration in suitable platforms.[4] This presentation will summarize the recent progress on MOF crystal engineering aspects, such as the functionalization of MOFs[5,6,7] and the controlled growth of MOFs on substrates.[8,9]
References
(1) Furukawa, H.; Cordova, K. E.; O’Keeffe, M.; Yaghi, O. M. Science 2013, 341 (6149), 1230444.
(2) Kitagawa, S.; Kitaura, R.; Noro, S. Angew. Chem. Int. Ed. 2004, 43 (18), 2334–2375.
(3) Chem. Soc. Rev. 2014. 43, special issue on MOFs.
(4) Falcaro, P.; Ricco, R.; Doherty, C. M.; Liang, K.; Hill, A. J.; Styles, M. J. Chem. Soc. Rev. 2014, 43 (16), 5513–5560.
(5) Doherty, C. M.; Buso, D.; Hill, A. J.; Furukawa, S.; Kitagawa, S.; Falcaro, P. Acc. Chem. Res. 2014, 47 (2), 396–405.
(6) Zanchetta, E.; Malfatti, L.; Ricco, R.; Styles, M. J.; Lisi, F.; Coghlan, C. J.; Doonan, C. J.; Hill, A. J.; Brusatin, G.; Falcaro, P. Chem. Mater. 2015, 27 (3), 690–699.
(7) Ricco, R.; Malfatti, L.; Takahashi, M.; Hill, A. J.; Falcaro, P. J. Mater. Chem. A 2013, 1 (42), 13033–13045.
(8) Okada, K.; Ricco, R.; Tokudome, Y.; Styles, M. J.; Hill, A. J.; Takahashi, M.; Falcaro, P. Adv. Funct. Mater. 2014, 24 (14), 1969–1977.
(9) Toyao, T.; Liang, K.; Okada, K.; Ricco, R.; Styles, M. J.; Tokudome, Y.; Horiuchi, Y.; Hill, A. J.; Takahashi, M.; Matsuoka, M.; Falcaro, P. Inorg. Chem. 2015.
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