Institute of Solid State Physics


SS22WS22SS23WS23SS24WS24      Guidelines for Master Students

The Wonders of Entanglement: Carbon Nanotube Aerogel Formation and Applications
Adam Beois
Department of Engineering University of Cambridge Cambridge, UK CB21PF
https://www.amboies.com
11:15 - 12:15 Wednesday 27 February 2019 PH04136

The presentation will detail efforts over the past one and a half decades to bring large-scale carbon nanotube (CNT) synthesis to fruition. Insights from the production of this unique phenomena observed in the laboratory and commercial reactors will be conveyed. The research efforts over the last decade plus have begun to uncover aerosol phenomena that are still not yet well explained, chief among them the formation of a macroscopic aerogel out of the nanoscale tubes. Efforts to quantify the criteria for aerogel formation will be explained using molecular and Brownian dynamic simulations combined with joint continuum scale models. The models provide the time scales for CNT aggregation and reorientation (akin to colloidal polymer physics models) that are the basis for the aerogel formation. The adaptive methods developed to model long CNTs (up to 1 mm) within molecular dynamic simulations will be discussed in the context of broader aerosol applications to study particle surface chemistry, coalescence and fine-scale interactions.
Harnessing the full potential of large-scale CNT production has yet to be fully achieved, but is now close. A further densification of 10 times per reactor is needed for economical CNT production, thus motivating new reactor designs. Plasma-based processes appear to be promising in providing single reactor scale-up, and our efforts to date will be highlighted. Applications of the resulting materials are being trialed by automotive and aerospace partners. Initial prototypes are showing promise where the early adopters are interested in the CNT-based materials for thermal applications and electro-magnetic interference shielding. Stabilization of lithium-ion battery electrodes via CNTs shows promise for fast charging lithium ion batteries.